Centrifugal Distortion Analysis of the Microwave and Millimeter Wave Spectra of Deuterated Ketenes

نویسندگان

  • Laszlo Nemes
  • Manfred Winnewisser
چکیده

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namensnennung 4.0 Lizenz. Centrifugal Distortion Analysis of the Microwave and Millimeter Wave Spectra of Deuterated Ketenes 2

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Millimeter Wave Rotational Spectrum and Centrifugal Distortion

Intensive studies have been carried out on the rotational spectra of various isotopic species of ketene, H2C = C = 0 , since 1950 [ 1 6 ] . The centrifugal distortion analysis of ketene [3, 4 ] , together with information from additional infrared data [3, 5 ] , enabled Mallinson and Nemes [6] to reevaluate the molecular force field for ketene. Recently, microwave investigations on the higher ho...

متن کامل

FT-MWAND MILLIMETER WAVE SPECTROSCOPY OF PANHs: PHENANTHRIDINE, ACRIDINE, AND 1,10-PHENANTHROLINE

The pure rotational spectra of phenanthridine, acridine, and 1,10-phenanthroline, small polycyclic aromatic nitrogen heterocycle molecules (PANHs), have been measured and assigned from 2 to 85 GHz. An initial spectral assignment, guided by ab initio molecular orbital predictions, employed broadband Stark modulated millimeter wave absorption spectroscopy of a supersonic rotationally cold molecul...

متن کامل

Ground State Centrifugal Distortion Constants of Trans-Acrolein, CH2 = CH—CHO from the Microwave and Millimeter Wave Rotational Spectra

The pure rotational spectrum of trans-acrolein in the ground vibrational state has been assigned in the frequency region from 8 GHz to 180 GHz. The measured absorption lines encompass a-type transitions from the " R k , q Q i . qQs branches and 6-type transitions from the r P 0 , r P x , r P 2 , rR0 brandies for values of J up to 23. The rotational constants have been refined and all quartic an...

متن کامل

Microwave spectrum and structure of the dimethylamine dimer: Evidence for a cyclic structure

Rotational spectra have been measured for six isotopomers of the dimethylamine dimer using a Fourier-transform microwave spectrometer. No tunneling splittings were observed for either the aor c-type rotational transitions and the spectra could be fit to a rigid rotor Hamiltonian including centrifugal distortion terms. Possible dimer structures are discussed and compared to the experimentally de...

متن کامل

Superconducting Microstrip-Fed Antenna Coupled to a Microwave Kinetic Inductance Detector

A proper antenna to couple to a microstrip Microwave Kinetic Inductance Detector (MKID) is designed and simulated. A twin-slot microstrip-fed inline antenna is designed for frequency band of 600-720~GHz integrated with an elliptical lens and coupled to the MKID. A systematic design procedure for design of such antenna with microstrip inline feeding is presented. Whole structure of lens and twin...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2013